Sono-RAFT Polymerization in Aqueous Medium

TG McKenzie; E Colombo; Q Fu; M Ashokkumar; GG Qiao

Journal article

Sono-RAFT Polymerization in Aqueous Medium

TG McKenzie, E Colombo, Q Fu, M Ashokkumar, GG Qiao

Angewandte Chemie International Edition | WILEY-V C H VERLAG GMBH | Published : 2017

DOI: 10.1002/anie.201706771

Download PDF

Abstract

The ultrasonic irradiation of aqueous solution is demonstrated to be a suitable source of initiating radicals for a controlled radical polymerization when conducted in the presence of a thiocarbonylthio-containing reversible addition–fragmentation chain transfer (RAFT) agent. This allows for a highly “green” method of externally regulated/controlled polymerization with a potentially broad scope for polymerizable monomers and/or polymer structures.

University of Melbourne Researchers

Muthupandian Ashokkumar Author

Greg Qiao Author

Related Projects (2)

Engineering Macromolecular Architectures for Targeted Applications

The purpose of the project is to use intelligent design to synthesise highly complex polymer architectures for targeted applications. The ad..

Ultrasound-assisted fabrication of biofunctional materials

The project aims to develop a fundamental understanding of the mechanism involved in the synthetic process in order to control the physical ..

Grants

Awarded by Australian Research Council

Funding Acknowledgements

E.C. acknowledges the University of Melbourne for the award of MIRS/MIFRS. M.A. acknowledges financial support from the Australian Research Council via an ARC-DP (DP160102908). G.G.Q. acknowledges support from the Australian Research Council via a Future Fellowship (FT110100411).